Black marks on pool walls are usually algea, you will probabley get marks around the bottom of the walls and maybe on the bottom as well.
You maybe able to clear the marks short term by using lots of anti alg. and shock chlorine, but the only long term cure I have found is to regrout the tiles.
It is probable that the grout between the tiles is either gone or porous thus allowing the algea to grow and thrive.
I look after pools for friends while they are not here to help them out, three of the pools suffered from the same problem as you are having, one of the pools was regrouted last winter and is now a dream to look after.
Another problem you will have is having to use lots of expensive chemicals to keep the pool clean, algea eats the chlorine, once you have had you pool regrouted, your chemical useage will drop dramatically.
Your pool will look like new after it is regrouted.
Get some one in to quote your for a regrout.